Welcome to her purgatory! Catch Hart of Dixie this fall on The CW. Hart of Dixie videos: Watch Hart of Dixie full episodes, previews, clips, interviews and more video.Fast-talking New Yorker and brand new doctor Zoe Hart has it all figured out - after graduating top of her class from medical school, she’ll follow in her father's footsteps and become a cardio-thoracic surgeon. But when her dreams fall apart, Zoe decides to accept an offer from a stranger, Dr. Harley Wilkes, to work with him at his small practice in Bluebell, Alabama.